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Coudé-feed stellar spectral library - atmospheric parameters
Context. Empirical libraries of stellar spectra play an important rolein different fields. For example, they are used as reference for theautomatic determination of atmospheric parameters, or for buildingsynthetic stellar populations to study galaxies. The CFLIB(Coudé-feed library, Indo-US) database is at present one of themost complete libraries, in terms of its coverage of the atmosphericparameters space (T{eff}, log g and [Fe/H]) and wavelengthcoverage 3460-9464 Å at a resolution of 1 Å FWHM. Althoughthe atmospheric parameters of most of the stars were determined fromdetailed analyses of high-resolution spectra, for nearly 300 of the 1273stars of the library at least one of the three parameters is missing.For the others, the measurements, compiled from the literature, areinhomogeneous. Aims: In this paper, we re-determine theatmospheric parameters, directly using the CFLIB spectra, and comparethem to the previous studies. Methods: We use the ULySS programto derive the atmospheric parameters, using the ELODIE library as areference. Results: Based on comparisons with several previousstudies we conclude that our determinations are unbiased. For the 958 F,G, and K type stars the precision on T{eff}, log g, and[Fe/H] is respectively 43 K, 0.13 dex and 0.05 dex. For the 53 M starsthey are 82 K, 0.22 dex and 0.28 dex. And for the 260 OBA type stars therelative precision on T{eff} is 5.1%, and on log g, and[Fe/H] the precision is respectively 0.19 dex and 0.16 dex. Theseparameters will be used to re-calibrate the CFLIB fluxes and to producesynthetic spectra of stellar populations.Tables 2 and 3 are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/525/A71

Beryllium, Oxygen, and Iron Abundances in Extremely Metal-Deficient Stars
The abundance of beryllium in the oldest, most metal-poor stars acts asa probe of early star formation and Galactic chemical evolution. We haveanalyzed high-resolution, high signal-to-noise ratio Keck/HIRES spectraof 24 stars with [Fe/H] from -2.3 to -3.5 in order todetermine the history of Be abundance and explore the possibility of aBe plateau. We have determined stellar parameters of our samplespectroscopically, using equivalent widths of Fe I, Ti I, and Ti IIlines. We have determined O abundances from three OH features whichoccur in the same spectral region; this region is relatively uncrowdedand has a well determined continuum in these very/extremely metal-poorstars. We have supplemented this sample with reanalyzed spectra of 25stars from previous observations so that our total sample ranges in[Fe/H] from -0.5 to -3.5. Our results indicate that therelationship between Be and [Fe/H] continues to lower metallicities witha slope of 0.92 ± 0.04. Although there is no indication of aplateau with constant Be abundance, the four lowest metallicity stars(below [Fe/H] of -3.0) do show a Be enhancement relative to Fe atthe 1σ level. A single relationship between Be and [O/H] has aslope of 1.21 ± 0.08, but there is also a good fit with twoslopes: 1.59 above [O/H] = -1.6 and 0.74 for stars with [O/H]below -1.6. This change in slope could result from a change in thedominant production mechanism for Be. In the era of the formation of themore metal-poor stars, Be would be formed by acceleration of CNO atomsin the vicinity of SN II and in later times by high-energy cosmic-raysbombarding CNO in the ambient interstellar gas. We find an excellentcorrelation between [Fe/H] and [O/H] and show that [O/Fe] is near +1.0at [Fe/H] = -3.5 declining to 0 at [Fe/H] = 0.

Chemical Evolution of Zinc in the Galaxy
Not Available

Calibration of Strömgren uvby-H? photometry for late-type stars - a model atmosphere approach
Context: The use of model atmospheres for deriving stellar fundamentalparameters, such as T_eff, log g, and [Fe/H], will increase as we findand explore extreme stellar populations where empirical calibrations arenot yet available. Moreover, calibrations for upcoming large satellitemissions of new spectrophotometric indices, similar to the uvby-H?system, will be needed. Aims: We aim to test the power oftheoretical calibrations based on a new generation of MARCS models bycomparisons with observational photomteric data. Methods: Wecalculated synthetic uvby-H? colour indices from synthetic spectra.A sample of 367 field stars, as well as stars in globular clusters, isused for a direct comparison of the synthetic indices versus empiricaldata and for scrutinizing the possibilities of theoretical calibrationsfor temperature, metallicity, and gravity. Results: We show thatthe temperature sensitivity of the synthetic (b-y) colour is very closeto its empirical counterpart, whereas the temperature scale based uponH? shows a slight offset. The theoretical metallicity sensitivityof the m1 index (and for G-type stars its combination withc_1) is somewhat higher than the empirical one, based upon spectroscopicdeterminations. The gravity sensitivity of the synthetic c1index shows satisfactory behaviour when compared to obervations of Fstars. For stars cooler than the sun, a deviation is significant in thec1-(b-y) diagram. The theoretical calibrations of (b-y),(v-y), and c1 seem to work well for Pop II stars and lead toeffective temperatures for globular cluster stars supporting recentclaims that atomic diffusion occurs in stars near the turnoff point ofNGC 6397. Conclusions: Synthetic colours of stellar atmospherescan indeed be used, in many cases, to derive reliable fundamentalstellar parameters. The deviations seen when compared to observationaldata could be due to incomplete linelists but are possibly also due tothe effects of assuming plane-parallell or spherical geometry and LTE.Model colours are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/498/527

Carbon and Strontium Abundances of Metal-poor Stars
We present carbon and strontium abundances for 100 metal-poor starsmeasured from R~7000 spectra obtained with the Echellette Spectrographand Imager at the Keck Observatory. Using spectral synthesis of theG-band region, we have derived carbon abundances for stars ranging from[Fe/H]=-1.3 to [Fe/H]=-3.8. The formal errors are ~0.2 dex in [C/Fe].The strontium abundance in these stars was measured using spectralsynthesis of the resonance line at 4215 Å. Using these twoabundance measurements along with the barium abundances from ourprevious study of these stars, we show that it is possible to identifyneutron-capture-rich stars with our spectra. We find, as in otherstudies, a large scatter in [C/Fe] below [Fe/H]=-2. Of the stars with[Fe/H]<-2, 9%+/-4% can be classified as carbon-rich metal-poor stars.The Sr and Ba abundances show that three of the carbon-rich stars areneutron-capture-rich, while two have normal barium and strontium. Thisfraction of carbon enhanced stars is consistent with other studies thatinclude this metallicity range.The data presented herein were obtained at the W. M. Keck Observatory,which is operated as a scientific partnership among the CaliforniaInstitute of Technology, the University of California, and the NationalAeronautics and Space Administration. The observatory was made possibleby the generous financial support of the W. M. Keck Foundation.

Population Synthesis in the Blue. IV. Accurate Model Predictions for Lick Indices and UBV Colors in Single Stellar Populations
We present a new set of model predictions for 16 Lick absorption lineindices from Hδ through Fe5335 and UBV colors for single stellarpopulations with ages ranging between 1 and 15 Gyr, [Fe/H] ranging from-1.3 to +0.3, and variable abundance ratios. The models are based onaccurate stellar parameters for the Jones library stars and a new set offitting functions describing the behavior of line indices as a functionof effective temperature, surface gravity, and iron abundance. Theabundances of several key elements in the library stars have beenobtained from the literature in order to characterize the abundancepattern of the stellar library, thus allowing us to produce modelpredictions for any set of abundance ratios desired. We develop a methodto estimate mean ages and abundances of iron, carbon, nitrogen,magnesium, and calcium that explores the sensitivity of the variousindices modeled to those parameters. The models are compared to high-S/Ndata for Galactic clusters spanning the range of ages, metallicities,and abundance patterns of interest. Essentially all line indices arematched when the known cluster parameters are adopted as input.Comparing the models to high-quality data for galaxies in the nearbyuniverse, we reproduce previous results regarding the enhancement oflight elements and the spread in the mean luminosity-weighted ages ofearly-type galaxies. When the results from the analysis of blue and redindices are contrasted, we find good consistency in the [Fe/H] that isinferred from different Fe indices. Applying our method to estimate meanages and abundances from stacked SDSS spectra of early-type galaxiesbrighter than L*, we find mean luminosity-weighed ages of theorder of ~8 Gyr and iron abundances slightly below solar. Abundanceratios, [X/Fe], tend to be higher than solar and are positivelycorrelated with galaxy luminosity. Of all elements, nitrogen is the morestrongly correlated with galaxy luminosity, which seems to indicatesecondary nitrogen enrichment. If that interpretation is correct, thisresult may impose a lower limit of 50-200 Myr to the timescale of starformation in early-type galaxies. Unlike clusters, galaxies show asystematic effect whereby higher order, bluer, Balmer lines yieldyounger ages than Hβ. This age discrepancy is stronger for lowerluminosity galaxies. We examine four possible scenarios to explain thistrend. Contamination of the bluer indices by a metal-poor stellarpopulation with a blue horizontal branch cannot account for the data.Blue stragglers and abundance-ratio effects cannot be ruled out, as theycan potentially satisfy the data, even though this can only be achievedby resorting to extreme conditions, such as extremely high [O/Fe] orspecific blue-straggler frequencies. The most likely explanation is thepresence of small amounts of a young/intermediate-age stellar populationcomponent. We simulate this effect by producing two-component models andshow that they provide a reasonably good match to the data when the massfraction of the young component is typically a few percent. Ifconfirmed, this result implies star formation has been extended inearly-type galaxies, and more so in less massive galaxies, which seemsto lend support to the ``downsizing'' scenario. Moreover, it impliesthat stellar population synthesis models are capable of constraining notonly the mean ages of stellar populations in galaxies, but also theirage spread.

Measuring the Balmer Jump and the Effective Gravity in FGK Stars
It is difficult to accurately measure the effective gravity (logg) inlate-type stars using broadband (e.g., UBV or SDSS) or intermediate-band(uvby) photometric systems, especially when the stars can cover a rangeof metallicities and reddenings. However, simple spectroscopicobservational and data reduction techniques can yield accurate valuesfor logg through comparison of the Balmer jumps of low-resolutionspectra with recent grids of synthetic flux spectra.

Medium-resolution Isaac Newton Telescope library of empirical spectra - II. The stellar atmospheric parameters
We present a homogeneous set of stellar atmospheric parameters(Teff, logg, [Fe/H]) for MILES, a new spectral stellarlibrary covering the range λλ 3525-7500Å at2.3Å (FWHM) spectral resolution. The library consists of 985 starsspanning a large range in atmospheric parameters, from super-metal-rich,cool stars to hot, metal-poor stars. The spectral resolution, spectraltype coverage and number of stars represent a substantial improvementover previous libraries used in population synthesis models. Theatmospheric parameters that we present here are the result of aprevious, extensive compilation from the literature. In order toconstruct a homogeneous data set of atmospheric parameters we have takenthe sample of stars of Soubiran, Katz & Cayrel, which has very welldetermined fundamental parameters, as the standard reference system forour field stars, and have calibrated and bootstrapped the data fromother papers against it. The atmospheric parameters for our clusterstars have also been revised and updated according to recent metallicityscales, colour-temperature relations and improved set of isochrones.

Pulkovo compilation of radial velocities for 35495 stars in a common system.
Not Available

Medium-resolution Isaac Newton Telescope library of empirical spectra
A new stellar library developed for stellar population synthesismodelling is presented. The library consists of 985 stars spanning alarge range in atmospheric parameters. The spectra were obtained at the2.5-m Isaac Newton Telescope and cover the range λλ3525-7500 Å at 2.3 Å (full width at half-maximum) spectralresolution. The spectral resolution, spectral-type coverage,flux-calibration accuracy and number of stars represent a substantialimprovement over previous libraries used in population-synthesis models.

uvby-β photometry of high-velocity and metal-poor stars. XI. Ages of halo and old disk stars
New uvby-β data are provided for 442 high-velocity and metal-poorstars; 90 of these stars have been observed previously by us, and 352are new. When combined with our previous two photometric catalogues, thedata base is now made up of 1533 high-velocity and metal-poor stars, allwith uvby-β photometry and complete kinematic data, such as propermotions and radial velocities taken from the literature. Hipparcos, plusa new photometric calibration for Mv also based on theHipparcos parallaxes, provide distances for nearly all of these stars;our previous photometric calibrations give values for E(b-y) and [Fe/H].The [Fe/H], V(rot) diagram allows us to separate these stars intodifferent Galactic stellar population groups, such as old-thin-disk,thick-disk, and halo. The X histogram, where X is our stellar-populationdiscriminator combining V(rot) and [Fe/H], and contour plots for the[Fe/H], V(rot) diagram both indicate two probable components to thethick disk. These population groups and Galactic components are studiedin the (b-y)0, Mv diagram, compared to theisochrones of Bergbusch & VandenBerg (2001, ApJ, 556, 322), toderive stellar ages. The two thick-disk groups have the meancharacteristics: ([Fe/H], V(rot), Age, σW') ≈ (-0.7dex, 120 km s-1, 12.5 Gyr, 62.0 km s-1), and≈(-0.4, 160, 10.0, 45.8). The seven most metal-poor halo groups,-2.31 ≤ [Fe/H] ≤ -1.31, show a mean age of 13.0 ± 0.2(mean error) Gyr, giving a mean difference from the WMAP results for theage of the Universe of 0.7 ± 0.3 Gyr. These results for the agesand components of the thick disk and for the age of the Galactic halofield stars are discussed in terms of various models and ideas for theformation of galaxies and their stellar populations.

Estimation of Carbon Abundances in Metal-Poor Stars. I. Application to the Strong G-Band Stars of Beers, Preston, and Shectman
We develop and test a method for the estimation of metallicities([Fe/H]) and carbon abundance ratios ([C/Fe]) for carbon-enhancedmetal-poor (CEMP) stars based on the application of artificial neuralnetworks, regressions, and synthesis models to medium-resolution (1-2Å) spectra and J-K colors. We calibrate this method by comparisonwith metallicities and carbon abundance determinations for 118 starswith available high-resolution analyses reported in the recentliterature. The neural network and regression approaches make use of apreviously defined set of line-strength indices quantifying the strengthof the Ca II K line and the CH G band, in conjunction with J-K colorsfrom the Two Micron All Sky Survey Point Source Catalog. The use ofnear-IR colors, as opposed to broadband B-V colors, is required becauseof the potentially large affect of strong molecular carbon bands onbluer color indices. We also explore the practicality of obtainingestimates of carbon abundances for metal-poor stars from the spectralinformation alone, i.e., without the additional information provided byphotometry, as many future samples of CEMP stars may lack such data. Wefind that although photometric information is required for theestimation of [Fe/H], it provides little improvement in our derivedestimates of [C/Fe], and hence, estimates of carbon-to-iron ratios basedsolely on line indices appear sufficiently accurate for most purposes.Although we find that the spectral synthesis approach yields the mostaccurate estimates of [C/Fe], in particular for the stars with thestrongest molecular bands, it is only marginally better than is obtainedfrom the line index approaches. Using these methods we are able toreproduce the previously measured [Fe/H] and [C/Fe] determinations withan accuracy of ~0.25 dex for stars in the metallicity interval-5.5<=[Fe/H]<=-1.0 and with 0.2<=(J-K)0<=0.8. Athigher metallicity, the Ca II K line begins to saturate, especially forthe cool stars in our program, and hence, this approach is not useful insome cases. As a first application, we estimate the abundances of [Fe/H]and [C/Fe] for the 56 stars identified as possibly carbon-rich, relativeto stars of similar metal abundance, in the sample of ``strong G-band''stars discussed by Beers, Preston, and Shectman.

A New Definition for the Ca4227 Feature: Is Calcium Really Underabundant in Early-Type Galaxies?
We have investigated the abundance of calcium in early-type galaxies bymeasuring the strength of the Ca I λ4227 absorption line in theirintegrated spectra. The database used is the large sample of early-typegalaxy integrated spectra in Caldwell and coworkers. We have measured Caabundances from the Ca I λ4227 feature both by using the LickCa4227 index and by defining a new index, Ca4227r, thatavoids the CN4216 molecular band in the continuum on the blueward sideof the line. With the new index definition we measure Ca abundances thatare systematically ~0.3 dex higher than with the Lick Ca4227 index. Theresult is that with the new index definition we obtain higher [Ca/Fe]abundances in early-type galaxies, which are more consistent with theirwell-known [Mg/Fe] overabundances. Hence, we suggest that Ca might beslightly enhanced, relative to Fe, in early-type galaxies.

Sulphur abundances in metal-poor stars
We investigate the debated "sulphur discrepancy" found among metal-poorstars of the Galactic halo with [Fe/H] < -2. This discrepancy stemsin part from the use of two different sets of sulphur lines, the veryweak triplet at 8694-95 Å and the stronger triplet lines at9212-9238 Å. For three representative cases of metal-poor dwarf,turnoff and subgiant stars, we argue that the abundances from theλλ8694-95 lines have been overestimated which has led to acontinually rising trend of [S/Fe] as metallicity decreases. Given thatthe near-IR region is subject to CCD fringing, these weak lines becomeexcessively difficult to measure accurately in the metallicity regime of[Fe/H] < -2. Based on homogeneously determined spectroscopic stellarparameters, we also present updated [S/Fe] ratios from theλλ9212-9238 lines which suggest a plateau-like behavioursimilar to that seen for other alpha elements.

The lithium content of the Galactic Halo stars
Thanks to the accurate determination of the baryon density of theuniverse by the recent cosmic microwave background experiments, updatedpredictions of the standard model of Big Bang nucleosynthesis now yieldthe initial abundance of the primordial light elements withunprecedented precision. In the case of ^7Li, the CMB+SBBN value issignificantly higher than the generally reported abundances for Pop IIstars along the so-called Spite plateau. In view of the crucialimportance of this disagreement, which has cosmological, galactic andstellar implications, we decided to tackle the most critical issues ofthe problem by revisiting a large sample of literature Li data in halostars that we assembled following some strict selection criteria on thequality of the original analyses. In the first part of the paper wefocus on the systematic uncertainties affecting the determination of theLi abundances, one of our main goal being to look for the "highestobservational accuracy achievable" for one of the largest sets of Liabundances ever assembled. We explore in great detail the temperaturescale issue with a special emphasis on reddening. We derive four sets ofeffective temperatures by applying the same colour {T}_eff calibrationbut making four different assumptions about reddening and determine theLTE lithium values for each of them. We compute the NLTE corrections andapply them to the LTE lithium abundances. We then focus on our "best"(i.e. most consistent) set of temperatures in order to discuss theinferred mean Li value and dispersion in several {T}_eff and metallicityintervals. The resulting mean Li values along the plateau for [Fe/H]≤ 1.5 are A(Li)_NLTE = 2.214±0.093 and 2.224±0.075when the lowest effective temperature considered is taken equal to 5700K and 6000 K respectively. This is a factor of 2.48 to 2.81 (dependingon the adopted SBBN model and on the effective temperature range chosento delimit the plateau) lower than the CMB+SBBN determination. We findno evidence of intrinsic dispersion. Assuming the correctness of theCMB+SBBN prediction, we are then left with the conclusion that the Liabundance along the plateau is not the pristine one, but that halo starshave undergone surface depletion during their evolution. In the secondpart of the paper we further dissect our sample in search of newconstraints on Li depletion in halo stars. By means of the Hipparcosparallaxes, we derive the evolutionary status of each of our samplestars, and re-discuss our derived Li abundances. A very surprisingresult emerges for the first time from this examination. Namely, themean Li value as well as the dispersion appear to be lower (althoughfully compatible within the errors) for the dwarfs than for the turnoffand subgiant stars. For our most homogeneous dwarfs-only sample with[Fe/H] ≤ 1.5, the mean Li abundances are A(L)_NLTE = 2.177±0.071 and 2.215±0.074 when the lowest effective temperatureconsidered is taken equal to 5700 K and 6000 K respectively. This is afactor of 2.52 to 3.06 (depending on the selected range in {T}_eff forthe plateau and on the SBBN predictions we compare to) lower than theCMB+SBBN primordial value. Instead, for the post-main sequence stars thecorresponding values are 2.260±0.1 and 2.235±0.077, whichcorrespond to a depletion factor of 2.28 to 2.52. These results,together with the finding that all the stars with Li abnormalities(strong deficiency or high content) lie on or originate from the hotside of the plateau, lead us to suggest that the most massive of thehalo stars have had a slightly different Li history than their lessmassive contemporaries. In turn, this puts strong new constraints on thepossible depletion mechanisms and reinforces Li as a stellartomographer.

Sulfur Abundances in Metal-Poor Stars Based on OAO-1.88m/HIDES Spectra
The LTE abundances of sulfur (S) of 21 metal-poor stars and one normalstar were explored in the metallicity range of -3 < [Fe/H] ≤ 0,based on the equivalent widths of the S I (1) 9212, 9237Å and S I(6) 8693, 9894Å lines measured on high-resolution spectra, whichwere observed by the OAO 1.88-m telescope equipped with HIDES. Our mainresults are: (1) The abundances derived from the S I (6) lines areconsistent with those from the S I (1) lines among our sample stars inthe range of [Fe/H] > -2 with an average difference of +0.03 ±0.05 dex, whereas a significant discrepancy is observed in the range of[Fe/H] ≤ -2. (2) The behavior of [S(6)/Fe], versus [Fe/H] of ourhalo sample stars exhibits a nearly flat trend with an average of +0.62± 0.09 dex in the range of -3 < [Fe/H] < -1.25, and shows adistribution around +0.29 dex in -1.25 ≤ [Fe/H] ≤ -0.7. Oursample stars with -1.25 ≤ [Fe/H] ≤ -0.5 follow an increasingtrend with decreasing [Fe/H]. The behavior of [S(1)/Fe] of our samplestars also shows essentially the same trend as [S(6)/Fe], though it isquantitatively different. (3) The S behavior in the range of -3 <[Fe/H] ≤ 0 inferred from the abundances of multiplets 6 and 1 arequalitatively consistent with each other, and may be represented by acombination of a nearly flat trend and a linearly increasing trend withdecreasing [Fe/H]. A transition of the trend is likely to occur at[Fe/H] ˜ -1.5 dex.

A Catalog of Northern Stars with Annual Proper Motions Larger than 0.15" (LSPM-NORTH Catalog)
The LSPM catalog is a comprehensive list of 61,977 stars north of theJ2000 celestial equator that have proper motions larger than 0.15"yr-1 (local-background-stars frame). The catalog has beengenerated primarily as a result of our systematic search for high propermotion stars in the Digitized Sky Surveys using our SUPERBLINK software.At brighter magnitudes, the catalog incorporates stars and data from theTycho-2 Catalogue and also, to a lesser extent, from the All-SkyCompiled Catalogue of 2.5 million stars. The LSPM catalog considerablyexpands over the old Luyten (Luyten Half-Second [LHS] and New LuytenTwo-Tenths [NLTT]) catalogs, superseding them for northern declinations.Positions are given with an accuracy of <~100 mas at the 2000.0epoch, and absolute proper motions are given with an accuracy of ~8 masyr-1. Corrections to the local-background-stars propermotions have been calculated, and absolute proper motions in theextragalactic frame are given. Whenever available, we also give opticalBT and VT magnitudes (from Tycho-2, ASCC-2.5),photographic BJ, RF, and IN magnitudes(from USNO-B1 catalog), and infrared J, H, and Ks magnitudes(from 2MASS). We also provide an estimated V magnitude and V-J color fornearly all catalog entries, useful for initial classification of thestars. The catalog is estimated to be over 99% complete at high Galacticlatitudes (|b|>15deg) and over 90% complete at lowGalactic latitudes (|b|>15deg), down to a magnitudeV=19.0, and has a limiting magnitude V=21.0. All the northern starslisted in the LHS and NLTT catalogs have been reidentified, and theirpositions, proper motions, and magnitudes reevaluated. The catalog alsolists a large number of completely new objects, which promise to expandvery significantly the census of red dwarfs, subdwarfs, and white dwarfsin the vicinity of the Sun.Based on data mining of the Digitized Sky Surveys (DSSs), developed andoperated by the Catalogs and Surveys Branch of the Space TelescopeScience Institute (STScI), Baltimore.Developed with support from the National Science Foundation (NSF), aspart of the NASA/NSF NStars program.

Abundances of Extremely Metal-poor Star Candidates
We present chemical abundances for 110 stars identified inobjective-prism surveys as candidates for being very metal-poor. Theabundances are derived from high-S/N, intermediate-resolution spectraobtained with the Keck Observatory Echellette Spectrograph and Imager(ESI). An additional 25 stars with well-determined abundances rangingfrom [Fe/H]=-1.5 to -3.2 were observed and the results used to helpcalibrate our analysis and determine the accuracy of our abundancedeterminations. Abundances for the program stars were measured for Fe,Mg, Ca, Ti, Cr, and Ba with an accuracy of approximately 0.3 dex.Fifty-three of the stars in our sample have [Fe/H]<=-2, 22 have[Fe/H]<=-2.5, and 13 have [Fe/H]<=-2.9. Surprisingly,approximately one-third of the sample is relatively metal-rich, with[Fe/H]>-1.5. In addition to identifying a number of extremelymetal-poor stars, this study also shows that moderate-resolution spectraobtained with the Keck ESI yield relatively accurate abundances forstars as faint as V=14 with modest exposure time (~20 minutes). Thiscapability will prove useful if the so-far elusive stars at [Fe/H]<-4turn out to be mostly fainter than V=15.The data presented herein were obtained at the W. M. Keck Observatory,which is operated as a scientific partnership among the CaliforniaInstitute of Technology, the University of California, and the NationalAeronautics and Space Administration. The Observatory was made possibleby the generous financial support of the W. M. Keck Foundation.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

Cu and Zn in the early Galaxy
We present Cu and Zn abundances for 38 FGK stars, mostly dwarfs,spanning a metallicity range between solar and [Fe/H] = -3. Theabundances were obtained using Kurucz's local thermal equilibrium (LTE)model atmospheres and the near-UV lines of Cu I 3273.95 Å and Zn I3302.58 Å observed at high spectral resolution. The trend of[Cu/Fe] versus [Fe/H] is almost solar for [Fe/H] > -1 and thendecreases to a plateau <[Cu/Fe]> = -0.98 at [Fe/H] < -2.5,whereas the [Zn/Fe] trend is essentially solar for [Fe/H] > -2 andthen slightly increases at lower metallicities to an average value of<[Zn/Fe]> = +0.18. We compare our results with previous work onthese elements, and briefly discuss them in terms of nucleosynthesisprocesses. Predictions of halo chemical evolution fairly reproduce thetrends, especially the [Cu/Fe] plateau at very low metallicities, but toa lesser extent the higher [Zn/Fe] ratios at low metallicities,indicating possibly missing yields.

Galactic evolution of nitrogen
We present detailed spectroscopic analysis of nitrogen abundances in 31unevolved metal-poor stars analysed by spectral synthesis of the near-UVNH band at 3360 Å observed at high resolution with varioustelescopes. We found that [N/Fe] scales with that of iron in themetallicity range -3.1 <[Fe/H]<0 with the slope 0.01±0.02.Furthermore, we derive uniform and accurate (N/O) ratios using oxygenabundances from near-UV OH lines obtained in our previous studies. Wefind that a primary component of nitrogen is required to explain theobservations. The NH lines are discovered in the VLT/UVES spectra of thevery metal-poor subdwarfs G64-12 and LP815-43 indicating that thesestars are N rich. The results are compared with theoretical models andobservations of extragalactic H II regions and Damped Lyα systems.This is the first direct comparison of the (N/O) ratios in these objectswith those in Galactic stars.

The Indo-US Library of Coudé Feed Stellar Spectra
We have obtained spectra for 1273 stars using the 0.9 m coudéfeed telescope at Kitt Peak National Observatory. This telescope feedsthe coudé spectrograph of the 2.1 m telescope. The spectra havebeen obtained with the no. 5 camera of the coudé spectrograph anda Loral 3K×1K CCD. Two gratings have been used to provide spectralcoverage from 3460 to 9464 Å, at a resolution of ~1 Å FWHMand at an original dispersion of 0.44 Å pixel-1. For885 stars we have complete spectra over the entire 3460 to 9464 Åwavelength region (neglecting small gaps of less than 50 Å), andpartial spectral coverage for the remaining stars. The 1273 stars havebeen selected to provide broad coverage of the atmospheric parametersTeff, logg, and [Fe/H], as well as spectral type. The goal ofthe project is to provide a comprehensive library of stellar spectra foruse in the automated classification of stellar and galaxy spectra and ingalaxy population synthesis. In this paper we discuss thecharacteristics of the spectral library, viz., details of theobservations, data reduction procedures, and selection of stars. We alsopresent a few illustrations of the quality and information available inthe spectra. The first version of the complete spectral library is nowpublicly available from the National Optical Astronomy Observatory(NOAO) via ftp and http.

Empirically Constrained Color-Temperature Relations. II. uvby
A new grid of theoretical color indices for the Strömgren uvbyphotometric system has been derived from MARCS model atmospheres and SSGsynthetic spectra for cool dwarf and giant stars having-3.0<=[Fe/H]<=+0.5 and 3000<=Teff<=8000 K. Atwarmer temperatures (i.e., 8000-2.0. To overcome thisproblem, the theoretical indices at intermediate and high metallicitieshave been corrected using a set of color calibrations based on fieldstars having well-determined distances from Hipparcos, accurateTeff estimates from the infrared flux method, andspectroscopic [Fe/H] values. In contrast with Paper I, star clustersplayed only a minor role in this analysis in that they provided asupplementary constraint on the color corrections for cool dwarf starswith Teff<=5500 K. They were mainly used to test thecolor-Teff relations and, encouragingly, isochrones thatemploy the transformations derived in this study are able to reproducethe observed CMDs (involving u-v, v-b, and b-y colors) for a number ofopen and globular clusters (including M67, the Hyades, and 47 Tuc)rather well. Moreover, our interpretations of such data are verysimilar, if not identical, with those given in Paper I from aconsideration of BV(RI)C observations for the sameclusters-which provides a compelling argument in support of thecolor-Teff relations that are reported in both studies. Inthe present investigation, we have also analyzed the observedStrömgren photometry for the classic Population II subdwarfs,compared our ``final'' (b-y)-Teff relationship with thosederived empirically in a number of recent studies and examined in somedetail the dependence of the m1 index on [Fe/H].Based, in part, on observations made with the Nordic Optical Telescope,operated jointly on the island of La Palma by Denmark, Finland, Iceland,Norway, and Sweden, in the Spanish Observatorio del Roque de losMuchachos of the Instituto de Astrofisica de Canarias.Based, in part, on observations obtained with the Danish 1.54 mtelescope at the European Southern Observatory, La Silla, Chile.

Comparing Deep Mixing in Globular Cluster and Halo Field Giants: Carbon Abundance Data from the Literature
The behavior of carbon abundance as a function of luminosity is used tocompare the rates of deep mixing within red giants of four globularclusters and the Galactic halo field population. Measurements of [C/Fe]for the clusters M92, NGC 6397, M3, and M13 have been compiled from theliterature, together with the Gratton et al. data for halo field stars.Plots of [C/Fe] versus absolute visual magnitude show that forMV<+1.6 the rate of decline of carbon abundance withincreasing luminosity on the red giant branch isd[C/Fe]/dMV~0.22+/-0.03 among the field stars, as well as inM92, NGC 6397, and M3. Among giants fainter than MV=+1.6 thevariation of [C/Fe] with absolute magnitude is much less. The dataindicate that the rate at which deep mixing introduces carbon-depletedmaterial into the convective envelopes of field halo stars during theupper red giant branch phase of evolution is similar to that of manyglobular cluster giants. The notable exception appears to be M13, inwhich stars exhibit deep mixing at a greater rate; this may account forthe high incidence of very low oxygen abundances among the most luminousgiants in M13 in comparison to M3.

Oxygen Abundances in Metal-poor Stars
We present oxygen abundances derived from both the permitted andforbidden oxygen lines for 55 subgiants and giants with [Fe/H] valuesbetween -2.7 and solar with the goal of understanding the discrepancy inthe derived abundances. A first attempt, using Teff valuesfrom photometric calibrations and surface gravities from luminositiesobtained agreement between the indicators for turn-off stars, but thedisagreement was large for evolved stars. We find that the difference inthe oxygen abundances derived from the permitted and forbidden lines ismost strongly affected by Teff, and we derive a newTeff scale based on forcing the two sets of lines to give thesame oxygen abundances. These new parameters, however, do not agree withother observables, such as theoretical isochrones or Balmer-line profilebased Teff determinations. Our analysis finds thatone-dimensional, LTE analyses (with published non-LTE corrections forthe permitted lines) cannot fully resolve the disagreement in the twoindicators without adopting a temperature scale that is incompatiblewith other temperature indicators. We also find no evidence ofcircumstellar emission in the forbidden lines, removing such emission asa possible cause for the discrepancy.

Non-LTE Analysis of the Sodium Abundance of Metal-Poor Stars in the Galactic Disk and Halo
We performed an extensive non-LTE analysis of the neutral sodium linesof Na I 5683/5688, 5890/5896, 6154/6161, and 8183/8195 in disk/halostars of types F-K covering a wide metallicity range (-4 <≈[Fe/H] <≈ +0.4), using our own data as well as data collectedfrom the literature. For comparatively metal-rich disk stars (-1<≈ [Fe/H] <≈ +0.4) where the weaker 6154/6161 linesare the best abundance indicators, we confirmed [Na/Fe] ˜ 0 with an"upturn" (i.e., a shallow/broad dip around -0.5 <≈ [Fe/H]<≈ 0) as already reported in previous studies. For themetal-deficient halo stars, where the much stronger 5890/5896 or8183/8195 lines subject to considerable (negative) non-LTE correctionsamounting to 0.5 dex have to be used, our analysis suggests mildly"subsolar" [Na/Fe] values down to ˜ -0.4 (with a somewhat largescatter of ˜ ± 0.2 dex) on the average at the typical halometallicity of [Fe/H] ˜ -2, followed by a rise again to a near-solarratio of [Na/Fe] ˜ 0 at the very metal-poor regime [Fe/H] ˜ -3to -4. These results are discussed in comparison with the previousobservational studies along with the theoretical predictions from theavailable chemical evolution models.

Oxygen line formation in late-F through early-K disk/halo stars. Infrared O I triplet and [O I] lines
In order to investigate the formation of O I 7771-5 and [O I] 6300/6363lines, extensive non-LTE calculations for neutral atomic oxygen werecarried out for wide ranges of model atmosphere parameters, which areapplicable to early-K through late-F halo/disk stars of variousevolutionary stages.The formation of the triplet O I lines was found to be well described bythe classical two-level-atom scattering model, and the non-LTEcorrection is practically determined by the parameters of theline-transition itself without any significant relevance to the detailsof the oxygen atomic model. This simplifies the problem in the sensethat the non-LTE abundance correction is essentially determined only bythe line-strength (Wlambda ), if the atmospheric parametersof Teff, log g, and xi are given, without any explicitdependence of the metallicity; thus allowing a useful analytical formulawith tabulated numerical coefficients. On the other hand, ourcalculations lead to the robust conclusion that LTE is totally valid forthe forbidden [O I] lines.An extensive reanalysis of published equivalent-width data of O I 7771-5and [O I] 6300/6363 taken from various literature resulted in theconclusion that, while a reasonable consistency of O I and [O I]abundances was observed for disk stars (-1 <~ [Fe/H] <~ 0), theexistence of a systematic abundance discrepancy was confirmed between OI and [O I] lines in conspicuously metal-poor halo stars (-3 <~[Fe/H] <~ -1) without being removed by our non-LTE corrections, i.e.,the former being larger by ~ 0.3 dex at -3 <~ [Fe/H] <~ -2.An inspection of the parameter-dependence of this discordance indicatesthat the extent of the discrepancy tends to be comparatively lessenedfor higher Teff/log g stars, suggesting the preference ofdwarf (or subgiant) stars for studying the oxygen abundances ofmetal-poor stars.Tables 2, 5, and 7 are only available in electronic form, at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/402/343 and Table\ref{tab3} is only available in electronic form athttp://www.edpsciences.org

Improved Astrometry and Photometry for the Luyten Catalog. II. Faint Stars and the Revised Catalog
We complete construction of a catalog containing improved astrometry andnew optical/infrared photometry for the vast majority of NLTT starslying in the overlap of regions covered by POSS I and by the secondincremental Two Micron All Sky Survey (2MASS) release, approximately 44%of the sky. The epoch 2000 positions are typically accurate to 130 mas,the proper motions to 5.5 mas yr-1, and the V-J colors to0.25 mag. Relative proper motions of binary components are measured to 3mas yr-1. The false-identification rate is ~1% for11<~V<~18 and substantially less at brighter magnitudes. Theseimprovements permit the construction of a reduced proper-motion diagramthat, for the first time, allows one to classify NLTT stars intomain-sequence (MS) stars, subdwarfs (SDs), and white dwarfs (WDs). We inturn use this diagram to analyze the properties of both our catalog andthe NLTT catalog on which it is based. In sharp contrast to popularbelief, we find that NLTT incompleteness in the plane is almostcompletely concentrated in MS stars, and that SDs and WDs are detectedalmost uniformly over the sky δ>-33deg. Our catalogwill therefore provide a powerful tool to probe these populationsstatistically, as well as to reliably identify individual SDs and WDs.

HIPPARCOS age-metallicity relation of the solar neighbourhood disc stars
We derive age-metallicity relations (AMRs) and orbital parameters forthe 1658 solar neighbourhood stars to which accurate distances aremeasured by the HIPPARCOS satellite. The sample stars comprise 1382 thindisc stars, 229 thick disc stars, and 47 halo stars according to theirorbital parameters. We find a considerable scatter for thin disc AMRalong the one-zone Galactic chemical evolution (GCE) model. Orbits andmetallicities of thin disc stars show now clear relation each other. Thescatter along the AMR exists even if the stars with the same orbits areselected. We examine simple extension of one-zone GCE models whichaccount for inhomogeneity in the effective yield and inhomogeneous starformation rate in the Galaxy. Both extensions of the one-zone GCE modelcannot account for the scatter in age - [Fe/H] - [Ca/Fe] relationsimultaneously. We conclude, therefore, that the scatter along the thindisc AMR is an essential feature in the formation and evolution of theGalaxy. The AMR for thick disc stars shows that the star formationterminated 8 Gyr ago in the thick disc. As already reported by Grattonet al. (\cite{Gratton_et.al.2000}) and Prochaska et al.(\cite{Prochaska_et.al.2000}), thick disc stars are more Ca-rich thanthin disc stars with the same [Fe/H]. We find that thick disc stars showa vertical abundance gradient. These three facts, the AMR, verticalgradient, and [Ca/Fe]-[Fe/H] relation, support monolithic collapseand/or accretion of satellite dwarf galaxies as likely thick discformation scenarios. Tables 2 and 3 are only available in electronicform at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5)or via http:/ /cdsweb.u-strasbg.fr/ cgi-bin/qcat?J/ A+A/394/927

A Survey of Proper-Motion Stars. XVI. Orbital Solutions for 171 Single-lined Spectroscopic Binaries
We report 25,563 radial velocity measurements for 1359 single-linedstars in the Carney-Latham sample of 1464 stars selected for high propermotion. For 171 of these, we present spectroscopic orbital solutions. Wefind no obvious difference between the binary characteristics in thehalo and the disk populations. The observed frequency is the same, andthe period distributions are consistent with the hypothesis that the twosets of binaries were drawn from the same parent population. Thissuggests that metallicity in general, and radiative opacities inparticular, have little influence over the fragmentation process thatleads to short-period binaries. All the binaries with periods shorterthan 10 days have nearly circular orbits, while the binaries withperiods longer than 20 days exhibit a wide range of eccentricities and amedian value of 0.37. For the metal-poor high-velocity halo binaries inour sample, the transition from circular to eccentric orbits appears tooccur at about 20 days, supporting the conclusion that tidalcircularization on the main sequence is important for the oldestbinaries in the Galaxy. Some of the results presented here usedobservations made with the Multiple Mirror Telescope, a joint facilityof the Smithsonian Institution and the University of Arizona.

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