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Na, Mg and Al abundances as a population discriminant for nearby metal-poor stars
Aims.Parameters for 55 nearby metal-poor stars are determined usinghigh-resolution spectroscopy. Together with similar data taken from arecent analysis, they are used to show trends of their Galacticevolution with stellar [Fe/H] or [Mg/H] abundances. The separation ofabundance ratios between disk and halo stars is used as a basiccriterion for population membership. Methods.After carefulselection of a clean subsample free of suspected or known binaries andpeculiar stars, abundances of Mg, Na and Al are based on NLTE kineticequilibrium calculations applied to spectrum synthesis methods. Results.The relation between [Na/Mg] and [Fe/H] is a continuousenrichment through all three Galactic populations spanning a range ofvalues between a metal-poor plateau at [ Na/Mg] = -0.7 and solar values.[Al/Mg] displays a step-like difference between stars of the Galactichalo with overline[Al/Mg] ˜ -0.45 and the two disk populations withoverline[Al/Mg] ˜ +0.10. [Al/Mg] ratios, together with the [Mg/Fe]ratios, asymmetric drift velocities V, and stellar evolutionary ages,make possible the individual discrimination between stars of the thickdisk and the halo. At present, this evidence is limited by the smallnumber of stars, and by the theoretical and empirical uncertainties ofstellar age determinations, but it achieves a high significance. Conclusions.While the stellar sample is not complete with respect tospace volume, the resulting abundances indicate the necessity to revisecurrent models of chemical evolution to allow for an adequate productionof Al in early stellar generations.

Elemental abundance survey of the Galactic thick disc
We have performed an abundance analysis for F- and G- dwarfs of theGalactic thick-disc component. A sample of 176 nearby (d<= 150pc)thick-disc candidate stars was chosen from the Hipparcos catalogue andsubjected to a high-resolution spectroscopic analysis. Using accurateradial velocities combined with the Hipparcos astrometry, kinematics (U,V and W) and Galactic orbital parameters were computed. We estimate theprobability for a star to belong to the thin disc, the thick disc or thehalo. With a probability P>= 70 per cent taken as certain membership,we assigned 95 stars to the thick disc, 13 to the thin disc, and 20 tothe halo. The remaining 48 stars in the sample cannot be assigned withreasonable certainty to one of the three components.Abundances of C, O, Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni,Cu, Zn, Y, Ba, Ce, Nd and Eu have been obtained. The abundances for thethick-disc stars are compared with those for the thin-disc members fromReddy et al. The ratios of α-elements (O, Mg, Si, Ca and Ti) toiron for thick-disc stars show a clear enhancement compared to thin-discmembers in the range -0.3 < [Fe/H] < -1.2. There are also otherelements - Al, Sc, V, Co, and possibly Zn - which show enhanced ratiosto iron in the thick disc relative to the thin disc. The abundances ofNa, Cr, Mn, Ni and Cu (relative to Fe) are very similar for thin- andthick-disc stars. The dispersion in abundance ratios [X/Fe] at given[Fe/H] for thick-disc stars is consistent with the expected scatter dueto measurement errors, suggesting a lack of `cosmic' scatter.A few stars classified as members of the thick disc by our kinematiccriteria show thin-disc abundances. These stars, which appear older thanmost thin-disc stars, are also, on average, younger than the thick-discpopulation. They may have originated early in the thin-disc history, andbeen subsequently scattered to hotter orbits by collisions. The thickdisc may not include stars with [Fe/H] > -0.3. The observedcompositions of the thin and thick discs seem to be consistent with themodels of galaxy formation by hierarchical clustering in a Lambda colddark matter (ΛCDM) universe.

Beryllium in Disk and Halo Stars: Evidence for a Beryllium Dispersion in Old Stars
The study of Be in stars of differing metal content can elucidate theformation mechanisms and the Galactic chemical evolution of the lightelement, Be. We have obtained high-resolution, high signal-to-noiseratio (S/N) spectra of the resonance lines of Be II in eight stars withthe High Dispersion Spectrograph (HDS) on the 8.2 m Subaru Telescope onMauna Kea. Abundances of Be have been determined through spectrumsynthesis. The stars with [Fe/H] values greater than -1.1 conform to thepublished general trend of Be versus Fe. We have confirmed the high Beabundance in HD 94028 and have found a similarly high Be abundance inanother star, HD 132475, at the same metallicity: [Fe/H]=-1.5. These twostars are 0.5-0.6 dex higher in Be than the Be-Fe trend. While thatgeneral trend contains the evidence for a Galaxy-wide enrichment in Beand Fe, the higher than predicted Be abundances in those two stars showsthat there are also local Be enrichments. Possible enrichment mechanismsinclude hypernovae and multiple supernova explosions contained in asuperbubble. One of our stars, G64-37, has a very low metallicity of[Fe/H]=-3.2 we have determined its Be abundance to look for evidence ofa Be plateau. Its Be abundance appears to extend the Be-Fe trend tolower Fe abundances without any evidence for a plateau, as had beenindicated by a high Be abundance in another very metal-poor star,G64-12. Although these two stars have similar Be abundances within theerrors, it could be that their different Be values indicate a Bedispersion even at the lowest metallicities.Based on observations obtained with the Subaru Telescope.

The lithium content of the Galactic Halo stars
Thanks to the accurate determination of the baryon density of theuniverse by the recent cosmic microwave background experiments, updatedpredictions of the standard model of Big Bang nucleosynthesis now yieldthe initial abundance of the primordial light elements withunprecedented precision. In the case of ^7Li, the CMB+SBBN value issignificantly higher than the generally reported abundances for Pop IIstars along the so-called Spite plateau. In view of the crucialimportance of this disagreement, which has cosmological, galactic andstellar implications, we decided to tackle the most critical issues ofthe problem by revisiting a large sample of literature Li data in halostars that we assembled following some strict selection criteria on thequality of the original analyses. In the first part of the paper wefocus on the systematic uncertainties affecting the determination of theLi abundances, one of our main goal being to look for the "highestobservational accuracy achievable" for one of the largest sets of Liabundances ever assembled. We explore in great detail the temperaturescale issue with a special emphasis on reddening. We derive four sets ofeffective temperatures by applying the same colour {T}_eff calibrationbut making four different assumptions about reddening and determine theLTE lithium values for each of them. We compute the NLTE corrections andapply them to the LTE lithium abundances. We then focus on our "best"(i.e. most consistent) set of temperatures in order to discuss theinferred mean Li value and dispersion in several {T}_eff and metallicityintervals. The resulting mean Li values along the plateau for [Fe/H]≤ 1.5 are A(Li)_NLTE = 2.214±0.093 and 2.224±0.075when the lowest effective temperature considered is taken equal to 5700K and 6000 K respectively. This is a factor of 2.48 to 2.81 (dependingon the adopted SBBN model and on the effective temperature range chosento delimit the plateau) lower than the CMB+SBBN determination. We findno evidence of intrinsic dispersion. Assuming the correctness of theCMB+SBBN prediction, we are then left with the conclusion that the Liabundance along the plateau is not the pristine one, but that halo starshave undergone surface depletion during their evolution. In the secondpart of the paper we further dissect our sample in search of newconstraints on Li depletion in halo stars. By means of the Hipparcosparallaxes, we derive the evolutionary status of each of our samplestars, and re-discuss our derived Li abundances. A very surprisingresult emerges for the first time from this examination. Namely, themean Li value as well as the dispersion appear to be lower (althoughfully compatible within the errors) for the dwarfs than for the turnoffand subgiant stars. For our most homogeneous dwarfs-only sample with[Fe/H] ≤ 1.5, the mean Li abundances are A(L)_NLTE = 2.177±0.071 and 2.215±0.074 when the lowest effective temperatureconsidered is taken equal to 5700 K and 6000 K respectively. This is afactor of 2.52 to 3.06 (depending on the selected range in {T}_eff forthe plateau and on the SBBN predictions we compare to) lower than theCMB+SBBN primordial value. Instead, for the post-main sequence stars thecorresponding values are 2.260±0.1 and 2.235±0.077, whichcorrespond to a depletion factor of 2.28 to 2.52. These results,together with the finding that all the stars with Li abnormalities(strong deficiency or high content) lie on or originate from the hotside of the plateau, lead us to suggest that the most massive of thehalo stars have had a slightly different Li history than their lessmassive contemporaries. In turn, this puts strong new constraints on thepossible depletion mechanisms and reinforces Li as a stellartomographer.

CCD Photometry of M92
We present Johnson B and V photometry for the galactic globular clusterM92 (NGC 6341). Photometric results for a total of ˜ 30,000 starsare obtained and are plotted on a V versus (B-V) diagram. We fittheoretical isochrones to this diagram in order to get an estimate forthe age of M92. The age which we find is ˜ 16×109years with the following values for the metallicity and He-abundance:[Fe/H] = -2.03, Y = 0.235. The distance modulus to this cluster turnsout to be m - M = 14.6 in accordance with that obtained by Stetson &Harris (1988). We also perform stellar counts in order to produce aluminosity function which is successfully fitted by the same theoreticalmodels fitted to the colour-magnitude diagram.

Sulphur abundance in Galactic stars
We investigate sulphur abundance in 74 Galactic stars by using highresolution spectra obtained at ESO VLT and NTT telescopes. For the firsttime the abundances are derived, where possible, from three opticalmultiplets: Mult. 1, 6, and 8. By combining our own measurements withdata in the literature we assemble a sample of 253 stars in themetallicity range -3.2  [Fe/H]  +0.5. Two important features,which could hardly be detected in smaller samples, are obvious from thislarge sample: 1) a sizeable scatter in [S/Fe] ratios around [Fe/H]˜-1; 2) at low metallicities we observe stars with [S/Fe]˜ 0.4, aswell as stars with higher [S/Fe] ratios. The latter do not seem to bekinematically different from the former ones. Whether the latter findingstems from a distinct population of metal-poor stars or simply from anincreased scatter in sulphur abundances remains an open question.

Chemical abundances in 43 metal-poor stars
We have derived abundances of O, Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Fe,Ni, and Ba for 43 metal-poor field stars in the solar neighbourhood,most of them subgiants or turn-off-point stars with iron abundances[Fe/H] ranging from -0.4 to -3.0. About half of this sample has not beenspectroscopically analysed in detail before. Effective temperatures wereestimated from uvby photometry, and surface gravities primarily fromHipparcos parallaxes. The analysis is differential relative to the Sun,and was carried out with plane-parallel MARCS models. Various sources oferror are discussed and found to contribute a total error of about0.1-0.2 dex for most elements, while relative abundances, such as[Ca/Fe], are most probably more accurate. For the oxygen abundances,determined in an NLTE analysis of the 7774 Å triplet lines, theerrors may be somewhat larger. We made a detailed comparison withsimilar studies and traced the reasons for the, in most cases,relatively small differences. Among the results we find that [O/Fe]possibly increases beyond [Fe/H] = -1.0, though considerably less sothan in results obtained by others from abundances based on OH lines. Wedid not trace any tendency toward strong overionization of iron, andfind the excesses, relative to Fe and the Sun, of the α elementsMg, Si, and Ca to be smaller than those of O. We discuss someindications that also the abundances of different α elementsrelative to Fe vary and the possibility that some of the scatter aroundthe trends in abundances relative to iron may be real. This may supportthe idea that the formation of Halo stars occurred in smaller systemswith different star formation rates. We verify the finding by Gratton etal. (2003b, A&A, 406, 131) that stars that do not participate in therotation of the galactic disk show a lower mean and larger spread in [α/Fe] than stars participating in the general rotation. The latterstars also seem to show some correlation between [ α/Fe] androtation speed. We trace some stars with peculiar abundances, amongthese two Ba stars, HD 17072 and HD196944, the second already known to be rich in s elements.Finally we advocate that a spectroscopic study of a larger sample ofhalo stars with well-defined selection criteria is very important, inorder to add to the very considerable efforts that various groups havealready made.

Spectroscopic Properties of Cool Stars (SPOCS). I. 1040 F, G, and K Dwarfs from Keck, Lick, and AAT Planet Search Programs
We present a uniform catalog of stellar properties for 1040 nearby F, G,and K stars that have been observed by the Keck, Lick, and AAT planetsearch programs. Fitting observed echelle spectra with synthetic spectrayielded effective temperature, surface gravity, metallicity, projectedrotational velocity, and abundances of the elements Na, Si, Ti, Fe, andNi, for every star in the catalog. Combining V-band photometry andHipparcos parallaxes with a bolometric correction based on thespectroscopic results yielded stellar luminosity, radius, and mass.Interpolating Yonsei-Yale isochrones to the luminosity, effectivetemperature, metallicity, and α-element enhancement of each staryielded a theoretical mass, radius, gravity, and age range for moststars in the catalog. Automated tools provide uniform results and makeanalysis of such a large sample practical. Our analysis method differsfrom traditional abundance analyses in that we fit the observed spectrumdirectly, rather than trying to match equivalent widths, and wedetermine effective temperature and surface gravity from the spectrumitself, rather than adopting values based on measured photometry orparallax. As part of our analysis, we determined a new relationshipbetween macroturbulence and effective temperature on the main sequence.Detailed error analysis revealed small systematic offsets with respectto the Sun and spurious abundance trends as a function of effectivetemperature that would be inobvious in smaller samples. We attempted toremove these errors by applying empirical corrections, achieving aprecision per spectrum of 44 K in effective temperature, 0.03 dex inmetallicity, 0.06 dex in the logarithm of gravity, and 0.5 kms-1 in projected rotational velocity. Comparisons withprevious studies show only small discrepancies. Our spectroscopicallydetermined masses have a median fractional precision of 15%, but theyare systematically 10% higher than masses obtained by interpolatingisochrones. Our spectroscopic radii have a median fractional precisionof 3%. Our ages from isochrones have a precision that variesdramatically with location in the Hertzsprung-Russell diagram. We planto extend the catalog by applying our automated analysis technique toother large stellar samples.

Abundance trends in kinematical groups of the Milky Way's disk
We have compiled a large catalogue of metallicities and abundance ratiosfrom the literature in order to investigate abundance trends of severalalpha and iron peak elements in the thin disk and the thick disk of theGalaxy. The catalogue includes 743 stars with abundances of Fe, O, Mg,Ca, Ti, Si, Na, Ni and Al in the metallicity range -1.30 < [Fe/H]< +0.50. We have checked that systematic differences betweenabundances measured in the different studies were lower than randomerrors before combining them. Accurate distances and proper motions fromHipparcos and radial velocities from several sources have been retreivedfor 639 stars and their velocities (U, V, W) and galactic orbits havebeen computed. Ages of 322 stars have been estimated with a Bayesianmethod of isochrone fitting. Two samples kinematically representative ofthe thin and thick disks have been selected, taking into account theHercules stream which is intermediate in kinematics, but with a probabledynamical origin. Our results show that the two disks are chemicallywell separated, they overlap greatly in metallicity and both showparallel decreasing alpha elements with increasing metallicity, in theinterval -0.80 < [Fe/H] < -0.30. The Mg enhancement with respectto Fe of the thick disk is measured to be 0.14 dex. An even largerenhancement is observed for Al. The thick disk is clearly older than thethin disk with tentative evidence of an AMR over 2-3 Gyr and a hiatus instar formation before the formation of the thin disk. We do not observea vertical gradient in the metallicity of the thick disk. The Herculesstream has properties similar to that of the thin disk, with a widerrange of metallicity. Metal-rich stars assigned to the thick disk andsuper-metal-rich stars assigned to the thin disk appear as outliers inall their properties.

Sulfur Abundances in Metal-Poor Stars Based on OAO-1.88m/HIDES Spectra
The LTE abundances of sulfur (S) of 21 metal-poor stars and one normalstar were explored in the metallicity range of -3 < [Fe/H] ≤ 0,based on the equivalent widths of the S I (1) 9212, 9237Å and S I(6) 8693, 9894Å lines measured on high-resolution spectra, whichwere observed by the OAO 1.88-m telescope equipped with HIDES. Our mainresults are: (1) The abundances derived from the S I (6) lines areconsistent with those from the S I (1) lines among our sample stars inthe range of [Fe/H] > -2 with an average difference of +0.03 ±0.05 dex, whereas a significant discrepancy is observed in the range of[Fe/H] ≤ -2. (2) The behavior of [S(6)/Fe], versus [Fe/H] of ourhalo sample stars exhibits a nearly flat trend with an average of +0.62± 0.09 dex in the range of -3 < [Fe/H] < -1.25, and shows adistribution around +0.29 dex in -1.25 ≤ [Fe/H] ≤ -0.7. Oursample stars with -1.25 ≤ [Fe/H] ≤ -0.5 follow an increasingtrend with decreasing [Fe/H]. The behavior of [S(1)/Fe] of our samplestars also shows essentially the same trend as [S(6)/Fe], though it isquantitatively different. (3) The S behavior in the range of -3 <[Fe/H] ≤ 0 inferred from the abundances of multiplets 6 and 1 arequalitatively consistent with each other, and may be represented by acombination of a nearly flat trend and a linearly increasing trend withdecreasing [Fe/H]. A transition of the trend is likely to occur at[Fe/H] ˜ -1.5 dex.

The Planet-Metallicity Correlation
We have recently carried out spectral synthesis modeling to determineTeff, logg, vsini, and [Fe/H] for 1040 FGK-type stars on theKeck, Lick, and Anglo-Australian Telescope planet search programs. Thisis the first time that a single, uniform spectroscopic analysis has beenmade for every star on a large Doppler planet search survey. We identifya subset of 850 stars that have Doppler observations sufficient todetect uniformly all planets with radial velocity semiamplitudes K>30m s-1 and orbital periods shorter than 4 yr. From this subsetof stars, we determine that fewer than 3% of stars with-0.5<[Fe/H]<0.0 have Doppler-detected planets. Above solarmetallicity, there is a smooth and rapid rise in the fraction of starswith planets. At [Fe/H]>+0.3 dex, 25% of observed stars have detectedgas giant planets. A power-law fit to these data relates the formationprobability for gas giant planets to the square of the number of metalatoms. High stellar metallicity also appears to be correlated with thepresence of multiple-planet systems and with the total detected planetmass. This data set was examined to better understand the origin of highmetallicity in stars with planets. None of the expected fossilsignatures of accretion are observed in stars with planets relative tothe general sample: (1) metallicity does not appear to increase as themass of the convective envelopes decreases, (2) subgiants with planetsdo not show dilution of metallicity, (3) no abundance variations for Na,Si, Ti, or Ni are found as a function of condensation temperature, and(4) no correlations between metallicity and orbital period oreccentricity could be identified. We conclude that stars with extrasolarplanets do not have an accretion signature that distinguishes them fromother stars; more likely, they are simply born in higher metallicitymolecular clouds.Based on observations obtained at Lick and Keck Observatories, operatedby the University of California, and the Anglo-Australian Observatories.

The Rise of the s-Process in the Galaxy
From newly obtained high-resolution, high signal-to-noise ratio spectrathe abundances of the elements La and Eu have been determined over thestellar metallicity range -3<[Fe/H]<+0.3 in 159 giant and dwarfstars. Lanthanum is predominantly made by the s-process in the solarsystem, while Eu owes most of its solar system abundance to ther-process. The changing ratio of these elements in stars over a widemetallicity range traces the changing contributions of these twoprocesses to the Galactic abundance mix. Large s-process abundances canbe the result of mass transfer from very evolved stars, so to identifythese cases we also report carbon abundances in our metal-poor stars.Results indicate that the s-process may be active as early as[Fe/H]=-2.6, although we also find that some stars as metal-rich as[Fe/H]=-1 show no strong indication of s-process enrichment. There is asignificant spread in the level of s-process enrichment even at solarmetallicity.

The Correlation of Lithium and Beryllium in F and G Field and Cluster Dwarf Stars
Although Li has been extensively observed in main-sequence field andcluster stars, there are relatively fewer observations of Be. We haveobtained Keck HIRES spectra of 36 late F and early G dwarfs in order tostudy the Li-Be correlation we found previously in the temperatureregime of 5900-6650 K. The sample size for this temperature range withdetectable and (usually) depleted Li and Be is now 88, including Li andBe abundances in both cluster and field stars. Therefore we can nowinvestigate the influence of other parameters such as age, temperature,and metallicity on the correlation. The Be spectra at 3130 Å weretaken over six nights from 1999 November to 2002 January and have aspectral resolution of ~48,000 and a median signal-to-noise ratio (S/N)of 108 pixel-1. We obtained Li spectra of 22 stars with theUniversity of Hawaii 88 inch (2.2 m) telescope and coudéspectrograph with a spectral resolution of ~70,000 and a median S/N of110 pixel-1. We have redetermined the effective temperaturesfor all the stars and adopted other parameters from published data orempirical relations. The abundances of both Li and Be in the stars weobserved were determined from spectrum synthesis with MOOG 2002. Thepreviously observed Li equivalent widths for some of our Be stars wereused with the new temperatures and MOOG 2002 in the ``blends'' mode. Forthe 46 field stars from this and earlier studies we find a linearrelation between A(Li) and A(Be) with a slope of 0.375+/-0.036. Over theTeff range 5900-6650 K, we find the modest scatter about theBe-Li relation to be significantly correlated with Teff andperhaps also [Fe/H]. Dividing the sample into two temperature regimes of6300-6650 K (corresponding to the cool side of the Li-Be dip) and5900-6300 K (corresponding to the Li ``plateau'') reveals possible smalldifferences in the slopes for the two groups, 0.404+/-0.034 and0.365+/-0.049, respectively. When we include the cluster stars (Hyades,Pleiades, Praesepe, UMa Group, and Coma), the slope for the fulltemperature range (88 stars) is essentially the same, at 0.382+/-0.030,as for the field stars alone. For the hotter temperature group of 35Li-Be dip stars in the field and in clusters the slope is higher, at0.433+/-0.036, while for the cooler star group (54 stars) the slope is0.337+/-0.031, different by more than 1 σ. This small differencein the slope is predicted by the theory of rotationally induced mixing.The four stars with [Fe/H] less than -0.4 are all below the best-fitrelation, i.e., there is more Be depletion at a given A(Li) or less Beab initio. The youngest stars, i.e., Pleiades, have less depletion ofboth Li and Be. This too is predicted by rotationally induced slowmixing. Combining the Be results from both field and cluster stars, wefind that there are stars with undepleted Be, i.e., near the meteoriticvalues of 1.42 dex, at all temperatures from 5500 to 6800 K. Depletionsof Be of up to and even exceeding 2 orders of magnitude are commonbetween 6000 and 6700 K.

Synthetic Lick Indices and Detection of α-enhanced Stars. II. F, G, and K Stars in the -1.0 < [Fe/H] < +0.50 Range
We present an analysis of 402 F, G, and K solar neighborhood stars, withaccurate estimates of [Fe/H] in the range -1.0 to +0.5 dex, aimed at thedetection of α-enhanced stars and at the investigation of theirkinematical properties. The analysis is based on the comparison of 571sets of spectral indices in the Lick/IDS system, coming from fourdifferent observational data sets, with synthetic indices computed withsolar-scaled abundances and with α-element enhancement. We useselected combinations of indices to single out α-enhanced starswithout requiring previous knowledge of their main atmosphericparameters. By applying this approach to the total data set, we obtain alist of 60 bona fide α-enhanced stars and of 146 stars withsolar-scaled abundances. The properties of the detected α-enhancedand solar-scaled abundance stars with respect to their [Fe/H] values andkinematics are presented. A clear kinematic distinction betweensolar-scaled and α-enhanced stars was found, although a one-to-onecorrespondence to ``thin disk'' and ``thick disk'' components cannot besupported with the present data.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

Cu and Zn in the early Galaxy
We present Cu and Zn abundances for 38 FGK stars, mostly dwarfs,spanning a metallicity range between solar and [Fe/H] = -3. Theabundances were obtained using Kurucz's local thermal equilibrium (LTE)model atmospheres and the near-UV lines of Cu I 3273.95 Å and Zn I3302.58 Å observed at high spectral resolution. The trend of[Cu/Fe] versus [Fe/H] is almost solar for [Fe/H] > -1 and thendecreases to a plateau <[Cu/Fe]> = -0.98 at [Fe/H] < -2.5,whereas the [Zn/Fe] trend is essentially solar for [Fe/H] > -2 andthen slightly increases at lower metallicities to an average value of<[Zn/Fe]> = +0.18. We compare our results with previous work onthese elements, and briefly discuss them in terms of nucleosynthesisprocesses. Predictions of halo chemical evolution fairly reproduce thetrends, especially the [Cu/Fe] plateau at very low metallicities, but toa lesser extent the higher [Zn/Fe] ratios at low metallicities,indicating possibly missing yields.

Galactic evolution of nitrogen
We present detailed spectroscopic analysis of nitrogen abundances in 31unevolved metal-poor stars analysed by spectral synthesis of the near-UVNH band at 3360 Å observed at high resolution with varioustelescopes. We found that [N/Fe] scales with that of iron in themetallicity range -3.1 <[Fe/H]<0 with the slope 0.01±0.02.Furthermore, we derive uniform and accurate (N/O) ratios using oxygenabundances from near-UV OH lines obtained in our previous studies. Wefind that a primary component of nitrogen is required to explain theobservations. The NH lines are discovered in the VLT/UVES spectra of thevery metal-poor subdwarfs G64-12 and LP815-43 indicating that thesestars are N rich. The results are compared with theoretical models andobservations of extragalactic H II regions and Damped Lyα systems.This is the first direct comparison of the (N/O) ratios in these objectswith those in Galactic stars.

Chromospheric Ca II Emission in Nearby F, G, K, and M Stars
We present chromospheric Ca II H and K activity measurements, rotationperiods, and ages for ~1200 F, G, K, and M type main-sequence stars from~18,000 archival spectra taken at Keck and Lick Observatories as a partof the California and Carnegie Planet Search Project. We have calibratedour chromospheric S-values against the Mount Wilson chromosphericactivity data. From these measurements we have calculated medianactivity levels and derived R'HK, stellar ages,and rotation periods from general parameterizations for 1228 stars,~1000 of which have no previously published S-values. We also presentprecise time series of activity measurements for these stars.Based on observations obtained at Lick Observatory, which is operated bythe University of California, and on observations obtained at the W. M.Keck Observatory, which is operated jointly by the University ofCalifornia and the California Institute of Technology. The KeckObservatory was made possible by the generous financial support of theW. M. Keck Foundation.

The Indo-US Library of Coudé Feed Stellar Spectra
We have obtained spectra for 1273 stars using the 0.9 m coudéfeed telescope at Kitt Peak National Observatory. This telescope feedsthe coudé spectrograph of the 2.1 m telescope. The spectra havebeen obtained with the no. 5 camera of the coudé spectrograph anda Loral 3K×1K CCD. Two gratings have been used to provide spectralcoverage from 3460 to 9464 Å, at a resolution of ~1 Å FWHMand at an original dispersion of 0.44 Å pixel-1. For885 stars we have complete spectra over the entire 3460 to 9464 Åwavelength region (neglecting small gaps of less than 50 Å), andpartial spectral coverage for the remaining stars. The 1273 stars havebeen selected to provide broad coverage of the atmospheric parametersTeff, logg, and [Fe/H], as well as spectral type. The goal ofthe project is to provide a comprehensive library of stellar spectra foruse in the automated classification of stellar and galaxy spectra and ingalaxy population synthesis. In this paper we discuss thecharacteristics of the spectral library, viz., details of theobservations, data reduction procedures, and selection of stars. We alsopresent a few illustrations of the quality and information available inthe spectra. The first version of the complete spectral library is nowpublicly available from the National Optical Astronomy Observatory(NOAO) via ftp and http.

The Luminosity Function and Color-Magnitude Diagram of the Globular Cluster M12
In this paper we present the V and I luminosity functions andcolor-magnitude diagrams derived from wide-field(23'×23') BVI photometry of theintermediate-metallicity ([Fe/H]~-1.3) Galactic globular cluster M12.Using observed values (and ranges of values) for the clustermetallicity, reddening, distance modulus, and age, we compare these datawith recent α-enhanced stellar evolution models for low-massmetal-poor stars. We describe several methods of making comparisonsbetween theoretical and observed luminosity functions to isolate theevolutionary timescale information that the luminosity functionscontain. We find no significant evidence of excesses of stars on the redgiant branch, although the morphology of the subgiant branch in theobserved luminosity function does not match theoretical predictions in asatisfactory way. Current uncertainties in Teff-colortransformations (and possibly also in other physics inputs to themodels) make more detailed conclusions about the subgiant branchmorphology impossible. Given the recent constraints on cluster ages fromthe WMAP experiment, we find that good-fitting models that do notinclude He diffusion (both color-magnitude diagrams and luminosityfunctions) are too old (by ~1-2 Gyr) to adequately represent the clusterluminosity function. The inclusion of helium diffusion in the modelsprovides an age reduction (compared with nondiffusive models) that isconsistent with the age of the universe being 13.7+/-0.2 Gyr.

Magnesium abundances in mildly metal-poor stars from different indicators
We present Mg abundances derived from high-resolution spectra usingseveral MgI and two high-excitation MgII lines for 19 metal-poor starswith [Fe/H] values between -1.1 and +0.2. The main goal is to search forsystematic differences in the derived abundances between the twoionization state lines. Our analysis shows that the one-dimensionallocal thermodynamic equilibrium (LTE) and non-LTE (N-LTE) study finds avery good agreement between these features. The [Mg/Fe] versus [Fe/H]relationship derived, despite the small sample of stars, is also inagreement with the classical figure of increasing [Mg/Fe] withdecreasing metallicity. We find a significant scatter however, in the[Mg/Fe] ratio at [Fe/H]~-0.6 which is currently explained as aconsequence of the overlap at this metallicity of thick- and thin-discstars, which were probably formed from material with differentnucleosynthesis histories. We speculate on the possible consequences ofthe agreement found between MgI and MgII lines on the very well-known Oproblem in metal-poor stars. We also study the [O/Mg] ratio in thesample stars using O abundances from the literature and find that thecurrent observations and nucleosynthetic predictions from Type IIsupernovae disagree. We briefly discuss some alternatives to solve thisdiscrepancy.

The Geneva-Copenhagen survey of the Solar neighbourhood. Ages, metallicities, and kinematic properties of ˜14 000 F and G dwarfs
We present and discuss new determinations of metallicity, rotation, age,kinematics, and Galactic orbits for a complete, magnitude-limited, andkinematically unbiased sample of 16 682 nearby F and G dwarf stars. Our˜63 000 new, accurate radial-velocity observations for nearly 13 500stars allow identification of most of the binary stars in the sampleand, together with published uvbyβ photometry, Hipparcosparallaxes, Tycho-2 proper motions, and a few earlier radial velocities,complete the kinematic information for 14 139 stars. These high-qualityvelocity data are supplemented by effective temperatures andmetallicities newly derived from recent and/or revised calibrations. Theremaining stars either lack Hipparcos data or have fast rotation. Amajor effort has been devoted to the determination of new isochrone agesfor all stars for which this is possible. Particular attention has beengiven to a realistic treatment of statistical biases and errorestimates, as standard techniques tend to underestimate these effectsand introduce spurious features in the age distributions. Our ages agreewell with those by Edvardsson et al. (\cite{edv93}), despite severalastrophysical and computational improvements since then. We demonstrate,however, how strong observational and theoretical biases cause thedistribution of the observed ages to be very different from that of thetrue age distribution of the sample. Among the many basic relations ofthe Galactic disk that can be reinvestigated from the data presentedhere, we revisit the metallicity distribution of the G dwarfs and theage-metallicity, age-velocity, and metallicity-velocity relations of theSolar neighbourhood. Our first results confirm the lack of metal-poor Gdwarfs relative to closed-box model predictions (the ``G dwarfproblem''), the existence of radial metallicity gradients in the disk,the small change in mean metallicity of the thin disk since itsformation and the substantial scatter in metallicity at all ages, andthe continuing kinematic heating of the thin disk with an efficiencyconsistent with that expected for a combination of spiral arms and giantmolecular clouds. Distinct features in the distribution of the Vcomponent of the space motion are extended in age and metallicity,corresponding to the effects of stochastic spiral waves rather thanclassical moving groups, and may complicate the identification ofthick-disk stars from kinematic criteria. More advanced analyses of thisrich material will require careful simulations of the selection criteriafor the sample and the distribution of observational errors.Based on observations made with the Danish 1.5-m telescope at ESO, LaSilla, Chile, and with the Swiss 1-m telescope at Observatoire deHaute-Provence, France.Complete Tables 1 and 2 are only available in electronic form at the CDSvia anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/418/989

On the correlation of elemental abundances with kinematics among galactic disk stars
We have performed the detailed analysis of 174 high-resolution spectraof FGK dwarfs obtained with the ELODIE echelle spectrograph at theObservatoire de Haute-Provence. Abundances of Fe, Si and Ni have beendetermined from equivalent widths under LTE approximation, whereasabundances of Mg have been determined under NLTE approximation usingequivalent widths of 4 lines and profiles of 5 lines. Spatial velocitieswith an accuracy better than 1 km s-1, as well as orbits,have been computed for all stars. They have been used to define 2subsamples kinematically representative of the thin disk and the thickdisk in order to highlight their respective properties. A transitionoccurs at [Fe/H] =-0.3. Stars more metal-rich than this value have aflat distribution with Zmax;<1 kpc and σW<20 km s-1, and a narrow distribution of [α/Fe].There exist stars in this metallicity regime which cannot belong to thethin disk because of their excentric orbits, neither to the thick diskbecause of their low scale height. Several thin disk stars areidentified down to [Fe/H] =-0.80. Their Mg enrichment is lower thanthick disk stars with the same metallicity. We confirm from a largersample the results of Feltzing et al. (\cite{felt03}) and Bensby et al.(\cite{ben03}) showing a decrease of [α/Fe] with [Fe/H] in thethick disk interpreted as the signature of the SNIa which haveprogressively enriched the ISM with iron. However our data suggest thatthe star formation in the thick disk stopped when the enrichment was[Fe/H] =-0.30, [Mg/Fe] =+0.20, [Si/Fe] =+0.17. A vertical gradient in[α/Fe] may exist in the thick disk but should be confirmed with alarger sample. Finally we have identified 2 new candidates of the HR1614moving group.Based on spectra collected with the ELODIE spectrograph at the 1.93-mtelescope of the Observatoire de Haute Provence (France).Tables 3 and 8 are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/418/551

Lithium abundances of the local thin disc stars
Lithium abundances are presented for a sample of 181 nearby F and Gdwarfs with accurate Hipparcos parallaxes. The stars are on circularorbits about the Galactic centre and, hence, are identified as belongingto the thin disc. This sample is combined with two published surveys toprovide a catalogue of lithium abundances, metallicities ([Fe/H]),masses, and ages for 451 F-G dwarfs, almost all belonging to the thindisc. The lithium abundances are compared and contrasted with publishedlithium abundances for F and G stars in local open clusters. The fieldstars span a larger range in [Fe/H] than the clusters for which [Fe/H]~=0.0 +/- 0.2. The initial (i.e. interstellar) lithium abundance of thesolar neighbourhood, as derived from stars for which astration oflithium is believed to be unimportant, is traced from logɛ(Li) =2.2 at [Fe/H]=-1 to logɛ(Li) = 3.2 at +0.1. This form for theevolution is dependent on the assumption that astration of lithium isnegligible for the stars defining the relation. An argument is advancedthat this latter assumption may not be entirely correct, and, theevolution of lithium with [Fe/H] may be flatter than previouslysupposed. A sharp Hyades-like Li dip is not seen among the field starsand appears to be replaced by a large spread among lithium abundances ofstars more massive than the lower mass limit of the dip. Astration oflithium by stars of masses too low to participate in the Li dip isdiscussed. These stars show little to no spread in lithium abundance ata given [Fe/H] and mass.

Stars of Extragalactic Origin in the Solar Neighborhood
For 77 main-sequence F-G stars in the solar neighborhood with publishediron, magnesium, and europium abundances determined from high-dispersionspectra and with the ages estimated from theoretical isochrones, wecalculated the spatial velocities using Hipparcos data and the Galacticorbital elements. A comparison with the orbital elements of the globularclusters that are known to have been accreted by our Galaxy in the pastreveals stars of extragalactic origin. We show that the abundance ratiosof r- and alpha-elements in all the accreted stars differ sharply fromthose in the stars that are genetically associated with the Galaxy.According to current theoretical models, europium is produced mainly inlow-mass type-II supernovae (SNe II), while magnesium is synthesized inlarge quantities in high-mass SN II progenitors. Since all the oldaccreted stars of our sample exhibit a significant Eu overabundancerelative to Mg, we conclude that the maximum masses of the SN IIprogenitors outside the Galaxy were much lower than those inside it. Onthe other hand, only a small number of young accreted stars exhibit lownegative ratios [Eu/Mg] < 0. This can be explained by the delay ofprimordial star formation and the explosions of high-mass SNe II in arelatively small part of extragalactic space. We provide evidence thatthe interstellar medium was weakly mixed at the early evolutionarystages of the Galaxy formed from a single protogalactic cloud, and thatthe maximum mass of the SN II progenitors increased in it with timesimultaneously with the increase in mean metallicity.

Neutron-Capture Elements in Halo, Thick-Disk, and Thin-Disk Stars: Neodymium
We have derived the LTE neodymium abundances in 60 cool stars withmetallicities [Fe/H] from 0.25 to -1.71 by applying a synthetic-spectrumanalysis to spectroscopic observations of NdII lines with a resolutionof λ/Δλ⋍60 000 and signal-to-noise ratios of100 200. We have improved the atomic parameters of NdII and blendinglines by analyzing the corresponding line pro files in the solarspectrum. Neodymium is overabundant with respect to iron in halo stars,[Nd/Fe]=0.33±0.09, with the [Nd/Fe] ratio decreasingsystematically with metallicity when [Fe/H]>-1. This reflects anonset of efficient iron production in type I supernovae during theformation of the thick disk. The [Nd/Ba] and [Nd/Eu] abundance ratiosbehave differently in halo, thick-disk, and thin-disk stars. Theobserved abundance ratios in halo stars, [Nd/Ba]=0.34±0.08 and[Nd/Eu]=-0.27±0.05, agree within the errors with the ratios ofthe elemental yields for the r-process. These results support theconclusion of other authors based on analyses of other elements that ther-process played the dominant role in the synthesis of heavy elementsduring the formation of the halo. The [Nd/Ba] and [Nd/Eu] ratios forthick-disk stars are almost independent of metallicity([Nd/Ba]=0.28(±0.03)-0.01(±0.04) [Fe/H] and[Nd/Eu]=-0.13(±0.03)+0.05(±0.04) [Fe/H]) but are smallerin absolute value than the corresponding ratios for halo stars,suggesting that the synthesis of s-process nuclei started during theformation of the thick disk. The s-process is estimated to havecontributed ⋍30% of the neodymium produced during this stage ofthe evolution of the Galaxy. The [Nd/Ba] ratio decreases abruptly by0.17 dex in the transition from the thick to the thin disk. Thesystematic decrease of [Nd/Ba] and increase of [Nd/Eu] with increasingmetallicity of thin-disk stars point toward a dominant role of thes-process in the synthesis of heavy elements during this epoch.

Empirically Constrained Color-Temperature Relations. II. uvby
A new grid of theoretical color indices for the Strömgren uvbyphotometric system has been derived from MARCS model atmospheres and SSGsynthetic spectra for cool dwarf and giant stars having-3.0<=[Fe/H]<=+0.5 and 3000<=Teff<=8000 K. Atwarmer temperatures (i.e., 8000-2.0. To overcome thisproblem, the theoretical indices at intermediate and high metallicitieshave been corrected using a set of color calibrations based on fieldstars having well-determined distances from Hipparcos, accurateTeff estimates from the infrared flux method, andspectroscopic [Fe/H] values. In contrast with Paper I, star clustersplayed only a minor role in this analysis in that they provided asupplementary constraint on the color corrections for cool dwarf starswith Teff<=5500 K. They were mainly used to test thecolor-Teff relations and, encouragingly, isochrones thatemploy the transformations derived in this study are able to reproducethe observed CMDs (involving u-v, v-b, and b-y colors) for a number ofopen and globular clusters (including M67, the Hyades, and 47 Tuc)rather well. Moreover, our interpretations of such data are verysimilar, if not identical, with those given in Paper I from aconsideration of BV(RI)C observations for the sameclusters-which provides a compelling argument in support of thecolor-Teff relations that are reported in both studies. Inthe present investigation, we have also analyzed the observedStrömgren photometry for the classic Population II subdwarfs,compared our ``final'' (b-y)-Teff relationship with thosederived empirically in a number of recent studies and examined in somedetail the dependence of the m1 index on [Fe/H].Based, in part, on observations made with the Nordic Optical Telescope,operated jointly on the island of La Palma by Denmark, Finland, Iceland,Norway, and Sweden, in the Spanish Observatorio del Roque de losMuchachos of the Instituto de Astrofisica de Canarias.Based, in part, on observations obtained with the Danish 1.54 mtelescope at the European Southern Observatory, La Silla, Chile.

On the Galactic chemical evolution of sulfur
Sulfur abundances have been determined for ten stars to resolve a debatein the literature on the Galactic chemical evolution of sulfur in thehalo phase of the Milky Way. Our analysis is based on observations ofthe S I lines at 9212.9, 9228.1, and 9237.5 Å for stars for whichthe S abundance was obtained previously from much weaker S I lines at8694.0 and 8694.6 Å. In contrast to the previous results showing[S/Fe] to rise steadily with decreasing [Fe/H], our results show that[S/Fe] is approximately constant for metal-poor stars ([Fe/H] -1)at [S/Fe] ≃ +0.3. Thus, sulfur behaves in a similar way to theother \alpha elements, with an approximately constant [S/Fe] formetallicities lower than [Fe/H]≃ -1. We suggest that the reasonfor the earlier claims of a rise of [S/Fe] is partly due to the use ofthe weak S I 8694.0 and 8694.6 Å lines and partly uncertainties inthe determination of the metallicity when using Fe I lines. The S I9212.9, 9228.1, and 9237.5 Å lines are preferred for an abundanceanalysis of sulfur for metal-poor stars.

First stars IV. CS 29497-030: Evidence for operation of the s-process at very low metallicity
We present an abundance analysis of the very metal-poor, carbon-enhancedstar CS 29497-030. Our results indicate that this unusually hot turnoffstar (Teff = 6650 K, log g = 3.5) has a metallicity [Fe/H] =-2.8, and exhibits large overabundances of carbon ([C/Fe] = +2.38),nitrogen ([N/Fe] = +1.88), and oxygen ([O/Fe] = +1.67). This star alsoexhibits a large enhancement in its neutron-capture elements; thepattern follows that expected to arise from the s-process. Inparticular, the Pb abundance is found to be very high with respect toiron ([Pb/Fe] = +3.5), and also with respect to the second peaks-process elements (e.g., Ba, La, Ce, Nd), which fits into the newlyintroduced classification of lead (Pb) stars. The known spectroscopicbinary status of this star, along with the observed s-process abundancepattern, suggest that it has accreted matter from a companion, whichformerly was an Asymptotic Giant-Branch (AGB) star. In a preliminaryanalysis, we have also identified broad absorption lines of metallicspecies that suggest a large axial rotational velocity for this star,which may be the result of spin-up associated with the accretion ofmaterial from its previous AGB companion. In addition, this star isclearly depleted in the light element Li. When considered along with itsrather high inferred temperature, these observations are consistent withthe expected properties of a very low metallicity halo blue straggler.Based on observations made with the ESO Very Large Telescope at ParanalObservatory, Chile (program ID 165.N-0276(A)).Table \ref{tab6} is only available in electronic form athttp://www.edpsciences.org

Oxygen Abundances in Metal-poor Stars
We present oxygen abundances derived from both the permitted andforbidden oxygen lines for 55 subgiants and giants with [Fe/H] valuesbetween -2.7 and solar with the goal of understanding the discrepancy inthe derived abundances. A first attempt, using Teff valuesfrom photometric calibrations and surface gravities from luminositiesobtained agreement between the indicators for turn-off stars, but thedisagreement was large for evolved stars. We find that the difference inthe oxygen abundances derived from the permitted and forbidden lines ismost strongly affected by Teff, and we derive a newTeff scale based on forcing the two sets of lines to give thesame oxygen abundances. These new parameters, however, do not agree withother observables, such as theoretical isochrones or Balmer-line profilebased Teff determinations. Our analysis finds thatone-dimensional, LTE analyses (with published non-LTE corrections forthe permitted lines) cannot fully resolve the disagreement in the twoindicators without adopting a temperature scale that is incompatiblewith other temperature indicators. We also find no evidence ofcircumstellar emission in the forbidden lines, removing such emission asa possible cause for the discrepancy.

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